Cao, Saichao; Xia, Mingxu; Jakse, Noel; Zeng, Long; Yu, Pengfei; Zhao, Yimeng; Lu, Wenquan; Li, Jianguo

SCRIPTA MATERIALIA

2024, 248, 1872-8456

Cao, Saichao; Xia, Mingxu; Jakse, Noel; Zeng, Long; Yu, Pengfei; Zhao, Yimeng; Lu, Wenquan; Li, Jianguo

The relationship among chemical composition, structure and glass-forming ability in multicomponent alloys is a long -standing puzzle due to the complexity of compositions. In this work, Al 77.8 Cu 22.2 and Al 70 Cu 20 Zr 10 amorphous alloy liquids were investigated by combining high-energy X-ray diffraction at a synchrotron facility, abinitio molecular dynamics and reverse Monte Carlo simulations. The analysis of short- and medium -range order structures of two liquid alloys show that the addition of Zr element increases the number of cluster types and makes the distribution of cluster content more uniform, and enhances the structural heterogeneity and correlation of clusters with high five-fold symmetry. These findings reveal the influence of Zr element on the atomic structure of the Al-Cu liquid alloy and deepen the understanding of Al-based metallic glasses formation.