Wang, Yanhao; Guo, Zhaoyang; Li, Yongchang; Black, Lachlan E.; MacDonald, Daniel H.; Bao, Shaojuan; Wang, Jilei; Zhang, Yongzhe; Zhang, Shan-Ting; Li, Dongdong

JOURNAL OF MATERIALS CHEMISTRY A

2024, 12, 2050-7496

Wang, Yanhao; Guo, Zhaoyang; Li, Yongchang; Black, Lachlan E.; MacDonald, Daniel H.; Bao, Shaojuan; Wang, Jilei; Zhang, Yongzhe; Zhang, Shan-Ting; Li, Dongdong

Carrier-selective passivating contacts in crystalline silicon (c-Si) solar cells have expanded from doped silicon films to non-silicon wide-bandgap materials to reduce parasitic absorption and production costs. Titanium oxide (TiOx) has emerged as one of the most promising materials and has achieved high performance in c-Si solar cells. In this work, TiOx is explored as a passivation interlayer in hole-selective contacts rather than conventional electron-selective contacts. Theoretical calculations and experimental results demonstrate that negative charges and shallow states in TiOx, derived from oxygen vacancies (VO), enhance surface passivation and assist hole tunneling, respectively. As a strategy to modulate VO, forming gas annealing is performed to further improve hole selectivity. By incorporating the TiOx passivation interlayer into MoOx-based c-Si solar cells, we achieve an improved efficiency and stability of the device, with the highest efficiency of 21.28%. This work advances the understanding of TiOx as a promising material to enhance hole selectivity for c-Si solar cells.